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Catalytic kinetics : chemistry and engineering / Dmitry Yu. Murzin and Tapio Salmi.

By: Murzin, Dmitry, 1963- [author.].
Contributor(s): Salmi, Tapio [author.].
Edition: Second edition.Description: xii, 740 pages : illustrations (some color) ; 24 cm.ISBN: 9780444637536; 0444637532.Subject(s): Catalysis | Chemical kinetics | Chemical kinetics | CatalysisDDC classification: 541/.395 Online resources: Available here
Contents:
History -- Catalysis -- Formal Kinetics -- Acquisition of Kinetic Data -- Kinetics and Thermodynamics -- Examples and Exercises -- Reference -- Homogeneous Catalysis -- Heterogeneous Catalysis -- Organocatalysis -- Examples and Exercises -- Reference -- Reaction Rate Theory -- Elementary Reactions in Solutions -- Reaction Mechanism -- Quasi-equilibrium Approximation -- Relationship Between Thermodynamics and Kinetics -- Transition State Theory of Surface Reactions -- Rates of Reactions on Nonideal Surfaces -- Deterministic and Stochastic Models -- Microkinetic Modeling -- Compensation Effect -- Isotope Effects -- Examples and Exercises -- References -- Steady State Kinetics of Complex Reactions -- Basic Routes of Complex Reactions -- Single-Route Steady-State Reaction -- Topological Analysis of Complex Reactions -- Electrical Analogy of Reaction Networks -- Thermodynamic Consistency of Rate Constants for Complex Networks -- Kinetic Aspects of Selectivity -- Parallel Reactions: Kinetic Coupling -- Reduction of Complexity -- Polynomial Kinetics -- Examples and Exercises -- References -- Homogeneous Acid-Base Catalysis -- Nucleophilic Catalysis -- Catalysis by Metal Ions -- Catalysis by Organometallic Complexes -- Organocatalysis -- Polymerization Catalysis -- Examples and Exercises -- References -- Enzymatic Catalysis -- Cooperative Kinetics -- Inhibition -- Effects of pH -- Single Molecule Enzymology -- Enantioselectivity in Enzyme Catalyzed Reactions -- Generalized Rate Laws for Enzymatic Reactions -- Heterogeneous Systems/Immobilized Enzymes -- Examples and Exercises -- References -- Reactions on Ideal Surfaces -- Reactions on Nonideal Surfaces -- Selectivity -- Polyatomic Nature of Reactants and Coverage-Dependent Adsorption Mode -- Solvent Effects -- Ionic Species -- Transfer of Labeled Atoms in Heterogeneous Catalytic Reactions -- Electrocatalytic Kinetics -- Photocatalytic Kinetics -- Nanokinetics -- Examples and Exercises -- References -- General -- Combined Catalytic and Noncatalytic Reactions -- Multiple Catalysts of the Same Type -- Multiple Catalysts of Different Types -- Examples and Exercises -- References -- Transient Kinetics -- Relaxation Methods -- Temperature-Programmed Desorption -- Oscillations -- Dynamic Catalyst Changes -- Examples and Exercises -- References -- Catalytic Multi-Phase Systems -- Simultaneous Reaction and Diffusion in Fluid Films and in Porous Materials -- Liquid-Liquid Diffusion, Phase-Transfer Catalysis -- Catalytic Two-Phase Systems -- Mass Transfer and Enzymatic Kinetics -- External Mass Transfer -- Internal Diffusion and Selectivity -- Internal Diffusion and Deactivation -- Elucidation of the Impact of Mass Transfer -- Three-Phase Systems -- Examples and Exercises -- References -- Basic Principles -- Heuristic Design of Experiments -- Parameter Estimation: Classical Methods -- Parameter Estimation: Regression -- Numerical Strategies -- Analysis of Parameters -- Model Discrimination -- Software -- Case Studies -- References.
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Shelves 		QD505 .M87 2016 (Browse shelf) Available 2000008787
Total holds: 0
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Includes bibliographical references and index.

Machine generated contents note: 1.1. History -- 1.2. Catalysis -- 1.3. Formal Kinetics -- 1.4. Acquisition of Kinetic Data -- 1.5. Kinetics and Thermodynamics -- 1.6. Examples and Exercises -- Reference -- 2.1. Homogeneous Catalysis -- 2.2. Heterogeneous Catalysis -- 2.3. Organocatalysis -- 2.4. Examples and Exercises -- Reference -- 3.1. Reaction Rate Theory -- 3.2. Elementary Reactions in Solutions -- 3.3. Reaction Mechanism -- 3.4. Quasi-equilibrium Approximation -- 3.5. Relationship Between Thermodynamics and Kinetics -- 3.6. Transition State Theory of Surface Reactions -- 3.7. Rates of Reactions on Nonideal Surfaces -- 3.8. Deterministic and Stochastic Models -- 3.9. Microkinetic Modeling -- 3.10. Compensation Effect -- 3.11. Isotope Effects -- 3.12. Examples and Exercises -- References -- 4.1. Steady State Kinetics of Complex Reactions -- 4.2. Basic Routes of Complex Reactions -- 4.3. Single-Route Steady-State Reaction -- 4.4. Topological Analysis of Complex Reactions -- 4.5. Electrical Analogy of Reaction Networks -- 4.6. Thermodynamic Consistency of Rate Constants for Complex Networks -- 4.7. Kinetic Aspects of Selectivity -- 4.8. Parallel Reactions: Kinetic Coupling -- 4.9. Reduction of Complexity -- 4.10. Polynomial Kinetics -- 4.11. Examples and Exercises -- References -- 5.1. Homogeneous Acid-Base Catalysis -- 5.2. Nucleophilic Catalysis -- 5.3. Catalysis by Metal Ions -- 5.4. Catalysis by Organometallic Complexes -- 5.5. Organocatalysis -- 5.6. Polymerization Catalysis -- 5.7. Examples and Exercises -- References -- 6.1. Enzymatic Catalysis -- 6.2. Cooperative Kinetics -- 6.3. Inhibition -- 6.4. Effects of pH -- 6.5. Single Molecule Enzymology -- 6.6. Enantioselectivity in Enzyme Catalyzed Reactions -- 6.7. Generalized Rate Laws for Enzymatic Reactions -- 6.8. Heterogeneous Systems/Immobilized Enzymes -- 6.9. Examples and Exercises -- References -- 7.1. Reactions on Ideal Surfaces -- 7.2. Reactions on Nonideal Surfaces -- 7.3. Selectivity -- 7.4. Polyatomic Nature of Reactants and Coverage-Dependent Adsorption Mode -- 7.5. Solvent Effects -- 7.6. Ionic Species -- 7.7. Transfer of Labeled Atoms in Heterogeneous Catalytic Reactions -- 7.8. Electrocatalytic Kinetics -- 7.9. Photocatalytic Kinetics -- 7.10. Nanokinetics -- 7.11. Examples and Exercises -- References -- 8.1. General -- 8.2. Combined Catalytic and Noncatalytic Reactions -- 8.3. Multiple Catalysts of the Same Type -- 8.4. Multiple Catalysts of Different Types -- 8.5. Examples and Exercises -- References -- 9.1. Transient Kinetics -- 9.2. Relaxation Methods -- 9.3. Temperature-Programmed Desorption -- 9.4. Oscillations -- 9.5. Dynamic Catalyst Changes -- 9.6. Examples and Exercises -- References -- 10.1. Catalytic Multi-Phase Systems -- 10.2. Simultaneous Reaction and Diffusion in Fluid Films and in Porous Materials -- 10.3. Liquid-Liquid Diffusion, Phase-Transfer Catalysis -- 10.4. Catalytic Two-Phase Systems -- 10.5. Mass Transfer and Enzymatic Kinetics -- 10.6. External Mass Transfer -- 10.7. Internal Diffusion and Selectivity -- 10.8. Internal Diffusion and Deactivation -- 10.9. Elucidation of the Impact of Mass Transfer -- 10.10. Three-Phase Systems -- 10.11. Examples and Exercises -- References -- 11.1. Basic Principles -- 11.2. Heuristic Design of Experiments -- 11.3. Parameter Estimation: Classical Methods -- 11.4. Parameter Estimation: Regression -- 11.5. Numerical Strategies -- 11.6. Analysis of Parameters -- 11.7. Model Discrimination -- 11.8. Software -- 11.9. Case Studies -- References.

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