Murzin, Dmitry, 1963-
Catalytic kinetics : chemistry and engineering / Dmitry Yu. Murzin and Tapio Salmi. - Second edition. - xii, 740 pages : illustrations (some color) ; 24 cm
Includes bibliographical references and index.
Machine generated contents note: History -- Catalysis -- Formal Kinetics -- Acquisition of Kinetic Data -- Kinetics and Thermodynamics -- Examples and Exercises -- Reference -- Homogeneous Catalysis -- Heterogeneous Catalysis -- Organocatalysis -- Examples and Exercises -- Reference -- Reaction Rate Theory -- Elementary Reactions in Solutions -- Reaction Mechanism -- Quasi-equilibrium Approximation -- Relationship Between Thermodynamics and Kinetics -- Transition State Theory of Surface Reactions -- Rates of Reactions on Nonideal Surfaces -- Deterministic and Stochastic Models -- Microkinetic Modeling -- Compensation Effect -- Isotope Effects -- Examples and Exercises -- References -- Steady State Kinetics of Complex Reactions -- Basic Routes of Complex Reactions -- Single-Route Steady-State Reaction -- Topological Analysis of Complex Reactions -- Electrical Analogy of Reaction Networks -- Thermodynamic Consistency of Rate Constants for Complex Networks -- Kinetic Aspects of Selectivity -- Parallel Reactions: Kinetic Coupling -- Reduction of Complexity -- Polynomial Kinetics -- Examples and Exercises -- References -- Homogeneous Acid-Base Catalysis -- Nucleophilic Catalysis -- Catalysis by Metal Ions -- Catalysis by Organometallic Complexes -- Organocatalysis -- Polymerization Catalysis -- Examples and Exercises -- References -- Enzymatic Catalysis -- Cooperative Kinetics -- Inhibition -- Effects of pH -- Single Molecule Enzymology -- Enantioselectivity in Enzyme Catalyzed Reactions -- Generalized Rate Laws for Enzymatic Reactions -- Heterogeneous Systems/Immobilized Enzymes -- Examples and Exercises -- References -- Reactions on Ideal Surfaces -- Reactions on Nonideal Surfaces -- Selectivity -- Polyatomic Nature of Reactants and Coverage-Dependent Adsorption Mode -- Solvent Effects -- Ionic Species -- Transfer of Labeled Atoms in Heterogeneous Catalytic Reactions -- Electrocatalytic Kinetics -- Photocatalytic Kinetics -- Nanokinetics -- Examples and Exercises -- References -- General -- Combined Catalytic and Noncatalytic Reactions -- Multiple Catalysts of the Same Type -- Multiple Catalysts of Different Types -- Examples and Exercises -- References -- Transient Kinetics -- Relaxation Methods -- Temperature-Programmed Desorption -- Oscillations -- Dynamic Catalyst Changes -- Examples and Exercises -- References -- Catalytic Multi-Phase Systems -- Simultaneous Reaction and Diffusion in Fluid Films and in Porous Materials -- Liquid-Liquid Diffusion, Phase-Transfer Catalysis -- Catalytic Two-Phase Systems -- Mass Transfer and Enzymatic Kinetics -- External Mass Transfer -- Internal Diffusion and Selectivity -- Internal Diffusion and Deactivation -- Elucidation of the Impact of Mass Transfer -- Three-Phase Systems -- Examples and Exercises -- References -- Basic Principles -- Heuristic Design of Experiments -- Parameter Estimation: Classical Methods -- Parameter Estimation: Regression -- Numerical Strategies -- Analysis of Parameters -- Model Discrimination -- Software -- Case Studies -- References. 1.1. 1.2. 1.3. 1.4. 1.5. 1.6. 2.1. 2.2. 2.3. 2.4. 3.1. 3.2. 3.3. 3.4. 3.5. 3.6. 3.7. 3.8. 3.9. 3.10. 3.11. 3.12. 4.1. 4.2. 4.3. 4.4. 4.5. 4.6. 4.7. 4.8. 4.9. 4.10. 4.11. 5.1. 5.2. 5.3. 5.4. 5.5. 5.6. 5.7. 6.1. 6.2. 6.3. 6.4. 6.5. 6.6. 6.7. 6.8. 6.9. 7.1. 7.2. 7.3. 7.4. 7.5. 7.6. 7.7. 7.8. 7.9. 7.10. 7.11. 8.1. 8.2. 8.3. 8.4. 8.5. 9.1. 9.2. 9.3. 9.4. 9.5. 9.6. 10.1. 10.2. 10.3. 10.4. 10.5. 10.6. 10.7. 10.8. 10.9. 10.10. 10.11. 11.1. 11.2. 11.3. 11.4. 11.5. 11.6. 11.7. 11.8. 11.9.
9780444637536 0444637532
2017385977
Catalysis.
Chemical kinetics.
Chemical kinetics
Catalysis.
QD505 / .M87 2016
541/.395
Catalytic kinetics : chemistry and engineering / Dmitry Yu. Murzin and Tapio Salmi. - Second edition. - xii, 740 pages : illustrations (some color) ; 24 cm
Includes bibliographical references and index.
Machine generated contents note: History -- Catalysis -- Formal Kinetics -- Acquisition of Kinetic Data -- Kinetics and Thermodynamics -- Examples and Exercises -- Reference -- Homogeneous Catalysis -- Heterogeneous Catalysis -- Organocatalysis -- Examples and Exercises -- Reference -- Reaction Rate Theory -- Elementary Reactions in Solutions -- Reaction Mechanism -- Quasi-equilibrium Approximation -- Relationship Between Thermodynamics and Kinetics -- Transition State Theory of Surface Reactions -- Rates of Reactions on Nonideal Surfaces -- Deterministic and Stochastic Models -- Microkinetic Modeling -- Compensation Effect -- Isotope Effects -- Examples and Exercises -- References -- Steady State Kinetics of Complex Reactions -- Basic Routes of Complex Reactions -- Single-Route Steady-State Reaction -- Topological Analysis of Complex Reactions -- Electrical Analogy of Reaction Networks -- Thermodynamic Consistency of Rate Constants for Complex Networks -- Kinetic Aspects of Selectivity -- Parallel Reactions: Kinetic Coupling -- Reduction of Complexity -- Polynomial Kinetics -- Examples and Exercises -- References -- Homogeneous Acid-Base Catalysis -- Nucleophilic Catalysis -- Catalysis by Metal Ions -- Catalysis by Organometallic Complexes -- Organocatalysis -- Polymerization Catalysis -- Examples and Exercises -- References -- Enzymatic Catalysis -- Cooperative Kinetics -- Inhibition -- Effects of pH -- Single Molecule Enzymology -- Enantioselectivity in Enzyme Catalyzed Reactions -- Generalized Rate Laws for Enzymatic Reactions -- Heterogeneous Systems/Immobilized Enzymes -- Examples and Exercises -- References -- Reactions on Ideal Surfaces -- Reactions on Nonideal Surfaces -- Selectivity -- Polyatomic Nature of Reactants and Coverage-Dependent Adsorption Mode -- Solvent Effects -- Ionic Species -- Transfer of Labeled Atoms in Heterogeneous Catalytic Reactions -- Electrocatalytic Kinetics -- Photocatalytic Kinetics -- Nanokinetics -- Examples and Exercises -- References -- General -- Combined Catalytic and Noncatalytic Reactions -- Multiple Catalysts of the Same Type -- Multiple Catalysts of Different Types -- Examples and Exercises -- References -- Transient Kinetics -- Relaxation Methods -- Temperature-Programmed Desorption -- Oscillations -- Dynamic Catalyst Changes -- Examples and Exercises -- References -- Catalytic Multi-Phase Systems -- Simultaneous Reaction and Diffusion in Fluid Films and in Porous Materials -- Liquid-Liquid Diffusion, Phase-Transfer Catalysis -- Catalytic Two-Phase Systems -- Mass Transfer and Enzymatic Kinetics -- External Mass Transfer -- Internal Diffusion and Selectivity -- Internal Diffusion and Deactivation -- Elucidation of the Impact of Mass Transfer -- Three-Phase Systems -- Examples and Exercises -- References -- Basic Principles -- Heuristic Design of Experiments -- Parameter Estimation: Classical Methods -- Parameter Estimation: Regression -- Numerical Strategies -- Analysis of Parameters -- Model Discrimination -- Software -- Case Studies -- References. 1.1. 1.2. 1.3. 1.4. 1.5. 1.6. 2.1. 2.2. 2.3. 2.4. 3.1. 3.2. 3.3. 3.4. 3.5. 3.6. 3.7. 3.8. 3.9. 3.10. 3.11. 3.12. 4.1. 4.2. 4.3. 4.4. 4.5. 4.6. 4.7. 4.8. 4.9. 4.10. 4.11. 5.1. 5.2. 5.3. 5.4. 5.5. 5.6. 5.7. 6.1. 6.2. 6.3. 6.4. 6.5. 6.6. 6.7. 6.8. 6.9. 7.1. 7.2. 7.3. 7.4. 7.5. 7.6. 7.7. 7.8. 7.9. 7.10. 7.11. 8.1. 8.2. 8.3. 8.4. 8.5. 9.1. 9.2. 9.3. 9.4. 9.5. 9.6. 10.1. 10.2. 10.3. 10.4. 10.5. 10.6. 10.7. 10.8. 10.9. 10.10. 10.11. 11.1. 11.2. 11.3. 11.4. 11.5. 11.6. 11.7. 11.8. 11.9.
9780444637536 0444637532
2017385977
Catalysis.
Chemical kinetics.
Chemical kinetics
Catalysis.
QD505 / .M87 2016
541/.395
